Ceramics crack, semiconductors chip and organic materials char, each under a different kind of thermal load. Femtosecond laser pulses are over before heat leaves the focal volume, so ceramic is milled, silicon and GaAs wafers are cut clean, organics are machined without burnt edges, and dielectric surfaces are activated for metallization.
Femtosecond processing of GaAs in air and water
Gallium arsenide (GaAs) is brittle and easily damaged by accumulated heat, so it is machined with femtosecond pulses. The result also depends on what surrounds the sample: the same pulses cut differently in ambient air and under a layer of water.
Trenches were milled in GaAs with a FemtoLux laser at 1030 nm and 900 fs, at repetition rates of 10, 50 and 200 kHz. Under a layer of water the trench depth nearly doubled, from 58 µm in ambient air to 105 µm, and the band of redeposited debris narrowed from 34 µm to 7.6 µm. Ablation efficiency was higher in water in all three regimes, about 9 µm³/µJ against 6 µm³/µJ at 10 kHz, and the gap narrowed as the repetition rate rose.
Trench milling parameters in water
| Regime No. | Average laser power | Pulse repetition rate | Scanning speed | Number of scans | Fluence | Hatch | Number of lines in scan | Trench depth |
|---|---|---|---|---|---|---|---|---|
| 1 | 0.4 W | 10 kHz | 50 mm/s | 14 | 13.1 J/cm2 | 10 µm | 11 | 105 µm |
| 2 | 2 W | 50 kHz | 250 mm/s | 14 | 13.1 J/cm2 | 10 µm | 11 | 99 µm |
| 3 | 8 W | 200 kHz | 1000 mm/s | 14 | 13.1 J/cm2 | 10 µm | 11 | 75 µm |
| Regime No. | Average laser power | Pulse repetition rate | Scanning speed | Number of scans | Fluence | Hatch | Number of lines in scan | Trench depth |
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Publications
Water-assisted ultrashort laser pulse processing of semiconductor materials is a promising technique to diminish heat accumulation and improve process quality. In this study, we investigate femtosecond laser ablation of deep trenches in GaAs, an important optoelectronic material, using water and ambient air environments at different laser processing regimes. We perform a comprehensive analysis of ablated trenches, including surface morphological analysis, atomic-resolution transmission electron microscopy imaging, elemental mapping, photoluminescence, and Raman spectroscopy. The findings demonstrate that GaAs ablation efficiency is enhanced in a water environment while heat-accumulation-related damage is reduced. Raman spectroscopy reveals a decrease in the broad feature associated with amorphous GaAs surface layers during water-assisted laser processing, suggesting that a higher material quality in deep trenches can be achieved using a water environment.